ࡱ> PRO !bjbj .&hh! !!!!!5555,a5@t}J$@,@.@.@.@.@.@.@$!BDR@!PPPR@!!g@P!!,@P,@<l?M5"j>*@}@0@>roEoET??VoE!\?PPPPPPPR@R@PPP@PPPPoEPPPPPPPPP : Green Chemistry Workshop Michael C. Cann, Chemistry Department, ̽, Scranton, PA 18510 570-941-7519  HYPERLINK "mailto:cannm1@uofs.edu" cannm1@uofs.edu Web site  HYPERLINK "http://academic.scranton.edu/faculty/CANNM1/" http://academic.scranton.edu/faculty/CANNM1/ I Sustainability Definition Environmental Impact Equation Ecological footprint Population Warming, greenhouse gases, Precautionary Principle energy consumption Transportation Food Water Housing Waste Forests, species extinction Sustainability & Chemistry II Introduction to Green Chemistry Environmental disasters in part caused by chemistry Command and control laws Pollution Prevention Act of 1990 The beginnings of Green Chemistry at the EPA Definition of Green Chemistry The Twelve Principles of Green Chemistry The spread of Green Chemistry The Presidential Green Chemistry Challenge Awards III Case studies in Green Chemistry (Presidential Green Chemistry Challenge Award winners) Pharmaceuticals IbuprofenSynthesis (atom economy)1,3,4 1998.5, 1997.1 Sertraline Synthesis2,4 (Zoloft) 2002.1 Biobased Compounds Biobased Propylene Glycol and Monomers from Natural Glycerin2,4 2006.5 PLA (Polylactic Acid); renewable feedstock; biodegradable plastic2,4 2002.2 Alternative solvents Surfactants for liquid & SC CO2 1,2,4 1997.5 Using Ionic Liquids to Dissolve and Process Cellulose for Advanced New Materials. 2,4 2005.6 Food Low Trans Fats and Oils Produced by Enzymatic Interesterification of Vegetable Oils2,4 2005.1 Pesticides Sentricon4 2000.3 Harpin2,4 2001.4 Wood preservatives ACQ Preserve, removing As and Cr2,4 2002.2 Chemicals employed in bleaching paper TAML (Tetraamido-macrocyclic activators for H2O2) 1,3,4 1999.5 Preparation of cotton (biocatalysts) Biopreparation of cotton4 2001.2 Removal of lead from automobile paint Yttrium in electrodeposition coatings2,4 2001.3 Fuels Catalytic Conversion of Plant Sugars into Liquid Hydrocarbon Fuels. 4 2009.4 Resources: 1) Real-World Cases in Green Chemistry, Cann, M. C. and Connelly, M. E, American Chemical Society, Washington, D.C., 2000. 2) Real-World Cases in Green Chemistry Volume II, Cann, M. C. and Umile, T.P., American Chemical Society, Washington, D.C.. 2008. 3)  HYPERLINK "http://academic.scranton.edu/faculty/CANNM1/greenchemistry.html" http://academic.scranton.edu/faculty/CANNM1/greenchemistry.html and links therein, especially  HYPERLINK "http://academic.scranton.edu/faculty/CANNM1/dreyfusmodules.html" http://academic.scranton.edu/faculty/CANNM1/dreyfusmodules.html 4) EPA site for the Presidential Green Chemistry Challenge Awards  HYPERLINK "http://www.epa.gov/greenchemistry/presgcc.html" http://www.epa.gov/greenchemistry/presgcc.html For sustainability:  HYPERLINK "http://www.earth-policy.org/index.php?/books/pb4" Plan B 4.0: Mobilizing to Save Civilization Lester R. 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